The Role of Sulphur Free Paper in Preventing Silver Tarnish and Oxidation in PCB Industry

The Role of Sulphur Free Paper in Preventing Silver Tarnish and Oxidation in PCB Industry
  • 2025-09-12 11:59:14

In the high-precision PCB (Printed Circuit Board) manufacturing industry, the quality and reliability of components are critical. Silver-plated pads are widely used to ensure conductivity and performance, but they are highly susceptible to tarnishing and oxidation caused by sulfur exposure in packaging materials and the environment.

This is where Sulphur Free Paper / Sulfur-Free Paper plays a key role. This specialized paper provides chemical stability and protection during storage, handling, and transportation. In this article, we explore its role in preventing silver tarnish, its applications, and why it is essential in the PCB industry.

What is Sulphur Free Paper?

Sulphur Free Paper, also called Sulfur-Free Paper, is a packaging material engineered with ultra-low sulfur content (typically ≤50mg/kg, SGS-certified). It prevents chemical reactions between sulfur and silver that could cause discoloration, tarnish, and conductivity degradation.

Key Features

  • Ultra-low sulfur content: SGS-certified for PCB and electronics applications.
  • Customizable grammage: 30g–250g for various protection needs.
  • Flexible formats: Available in sheets or rolls for manual or automated packaging.
  • Eco-compliant: RoHS and REACH friendly.
  • Anti-oxidation performance: Maintains silver plating brightness and conductivity.

Why Silver Tarnish is Critical in PCB Manufacturing

The Chemistry Behind Tarnish

When silver reacts with sulfur, it forms silver sulfide, appearing as black or dark discoloration. In PCB manufacturing, tarnished silver pads can:

  • Reduce solderability and cause faulty connections
  • Affect overall board reliability
  • Lead to higher rejection rates and increased production costs

Industry Risks

  • Electronics OEMs: Face warranty claims due to poor solderability.
  • Exporters: Risk product complaints during long-distance shipping.
  • Manufacturers: May encounter quality certification issues if oxidation occurs before assembly.

By using Sulphur Free Paper / Sulfur-Free Paper, PCB manufacturers mitigate these risks and ensure consistent quality.

Applications of Sulfur-Free Paper in PCB Industry

  • PCB interleaving and stacking: Prevents silver tarnish during storage and shipment.
  • Export packaging: Protects sensitive silver pads from oxidation during long-distance shipping.
  • High-value electronic components: Silver-plated connectors, terminals, and microelectronics are better preserved.

Benefits of Sulphur Free Paper

  • Prevents silver tarnish and oxidation
  • Extends shelf life for longer storage periods
  • Supports global compliance: SGS, RoHS standards
  • Reduces defects, rework, and product returns
  • Customizable thicknesses and formats for various applications

How to Choose the Right Sulfur-Free Paper

Step 1: Verify Certification

  • Request SGS reports confirming sulfur content
  • Ensure RoHS/REACH compliance

Step 2: Match Grammage to Application

  • 30–50g: Thin PCB interleaving and wafers
  • 60–120g: Standard PCB stacking and electronics packaging
  • 150–250g: Heavy-duty or export-grade protection

Step 3: Select Format

  • Rolls: Automated packaging lines
  • Sheets: Manual handling and stacking

Step 4: Consider Storage Conditions

  • Store at 18–25°C in dry conditions
  • Avoid direct sunlight, moisture, and contamination

FAQ – Sulphur Free Paper for PCB Industry

Q1: Can sulfur-free paper prevent tarnish during long-term storage?

Yes. Properly stored sulfur-free paper keeps silver pads safe for up to a year or more.

Q2: Is sulfur-free paper recyclable?

Yes, it is environmentally friendly and fully recyclable.

Q3: How do I choose between different paper weights?

  • Select based on PCB fragility and storage/shipping duration
  • Lighter weights for thin boards, heavier for stacked or heavy-duty boards

Q4: Does using sulfur-free paper increase shipping costs?

No. Sulfur-free paper is lightweight, so additional freight cost is minimal.

Conclusion

In PCB manufacturing, protecting silver-plated pads from tarnish and oxidation is essential. Sulphur Free Paper / Sulfur-Free Paper provides reliable chemical protection, maintains product quality, reduces defects, and supports global export compliance.

For PCB manufacturers, exporters, and electronics OEMs, integrating sulfur-free paper into packaging processes is a cost-effective solution to safeguard products, minimize losses, and maintain customer trust.

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